Adib Caidi spricht beim Hydrogen Energy Symposium 2024

Graded Catalysts in Fuel Cells – Increased Performance Without Higher Platinum Usage

Open access paper published in Energy Materials: Clever gradient design in catalyst layer makes fuel cells more efficient. Precious metals used only where necessary.

One approach to making fuel cells more powerful or more cost-effective, or both, is to optimise catalyst layers. Adib Caidi (pictured), a doctoral student at ZBT, has now published a study exploring the idea that gradients in the distribution of platinum, carbon and ionomer in the catalyst layer could

  • improve catalyst utilisation near the membrane,
  • improve gas diffusion and water management near the gas diffusion layer,
  • and balance ion conductivity across the catalyst layer.

His motto: maximum performance with minimum platinum.

Caidi systematically applied and investigated various composition gradients on pre-optimised, non-graded catalyst layers. He introduced passivation gradients in the categories of Pt/C loading, the ionomer-carbon ratio and the ionomer equivalent weight – both individually and in combination.

Electrochemical impedance spectroscopy was used to reveal the underlying transport and kinetic effects. ‘This strategy enabled us to clearly separate the contributions of kinetic, mass transport and ohmic resistance effects,’ explains Caidi.

Graded catalysts significantly increase performance

And the effort paid off: the fully graded catalyst ultimately showed a 32% increase in performance at 0.6 V (wet conditions) and a 17% increase at 0.6 V (dry conditions) compared to the pre-optimised reference. These results underscore the critical importance of combining robust base optimisation with a rational gradient design, which offers a comprehensive path to performance enhancement while minimising precious metal consumption.

Grafiken zu einer Studie über Gradienten-Design in Katalysatorschichten für PEM-Brennstoffzellen

These improvements directly address two of the most pressing challenges in fuel cell research: efficient catalyst utilisation and robust performance under water-limited operating conditions.

The publication is highly relevant to the field of research as it bridges the gap between fundamental electrochemical understanding and practical electrode design strategies. Through the systematic variation and analysis of gradient concepts, the study provides a blueprint for next-generation PEMFC electrodes and inspires new approaches in materials-oriented development research.

Beyond fuel cells, the methodology of combining base optimisation with gradient engineering can also be applied to electrolysers, underscoring the broad impact of this work. Its significance is also reflected in its publication in Energy Materials (impact factor 11.2) – a leading journal in the field of energy research that highlights the scientific and practical relevance of our findings.

The paper

Title: Gradient engineering in proton exchange membrane fuel cell cathodes: an electrochemical study of charge transfer, mass transport, and Pt utilisation

in Energy Materials

Author: Adib Caidi
Co-authors: Thomas Lange, Ivan Radev, Kerstin Grimm, Volker Peinecke, Fatih Özcan, Doris Segets

The publication is open access. Thanks to AK Science for covering the costs!

 

Electrochemical Components Department

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